This paper describes phytochemical studies on aerial part of the Cocculus pendulus, which led to the identification of a new ingredient namely, 1,2-dihydrokurramine (1) along with four reported compounds 1,2-Dehydrokohatine (2), Kohatine (3), and 5¢Hhydroxyapateline (4). Structures of all the Compounds were elucidated by using 1D and 2D NMR and mass spectroscopy. High Resolution Mass Spectroscopy (HRMS) afforded the exact mass to be 534.2160, which corresponded to the formula C₃₃H₃₀N₂O₅ (calc.534.2154). The mass spectrum exhibited molecular ion peak M⁺ at m/z 534. The characteristics of M⁺-212 peak at m/z 322 resulted from double benzylic cleavage.